MATERIAL SAFETY DATA SHEET CHASER庐 2 AMINE
FOR CHEMICAL EMERGENCY, SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT, CALL CHEMTREC - DAY OR NIGHT 1-800-424-9300
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
FORMULATED FOR:
VERDICON 24-Hour Emergency Phone: 1-800-424-9300
P.O. Box 1286 鈥? Greeley, CO 80632-1286 Medical Emergencies: 1-800-301-7976
PRODUCT NAME: CHASER庐 2 AMINE
CHEMICAL NAME: 2,4-Dichlorophenoxyacetic acid, dimethylamine salt and Triclopyr: 3,5,6-trichloro-2-pyridinyloxyacetic acid, triethylamine salt
CHEMICAL FAMILY: Phenoxy Herbicide
EPA REG. NO.: 228-316-65783
MSDS Number: 228316-04-VER MSDS Revisions: New Date Of Issue: 03/05/04 Supersedes: New
2. COMPOSITION, INFORMATION ON INGREDIENTS
Chemical Ingredients: Percentage by Weight: CAS No. TLV (Units)
3
2,4-D, dimethylamine salt* 34.20 2008-39-1 10 mg/m
Triclopyr, triethylamine salt** 15.20 57213-69-1 none established
Inert Ingredients, including 50.60
Unreacted triethylamine 121-44-8 none established
3. HAZARDS IDENTIFICATION SUMMARY
KEEP OUT OF REACH OF CHILDREN - DANGER 鈥? PELIGRO - Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted
en detaile (If you do not understand the label, find someone to explain it to you in detail.) Corrosive. Causes irreversible eye damage. Harmful if
swallowed or inhaled. Do not get in eyes, on skin, or on clothing.
This product is a clear amber liquid with mild amine odor.
4. FIRST AID MEASURES
If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
If swallowed: Call a poison control center or doctor immediately for treatment advice. Have a person sip a glass of water if able to swallow.
Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an
unconscious person.
If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or
doctor for treatment advice.
If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably
mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice.
Note to Physician: Probable mucosal damage may contraindicate use of gastric lavage.
FOR A MEDICAL EMERGENCY INVOLVING THIS PRODUCT CALL: 1-800-301-7976. Have the product label or container with you when calling a poison control
center or doctor, or going for treatment.
5. FIRE FIGHTING MEASURES
O O
FLASH POINT (掳F/Test Method): >202 F/>94.4 C (Seta flash)
FLAMMABLE LIMITS (LEL & UEL): Not established
EXTINGUISHING MEDIA: Use medium appropriate to surrounding fire. Dry chemical, carbon dioxide, foam, water spray or fog.
HAZARDOUS COMBUSTION PRODUCTS: May include but are not limited to hydrogen chloride and oxides of nitrogen.
SPECIAL FIRE FIGHTING PROCEDURES: Use water spray to cool containers exposed to fire. Remain upwind. Avoid breathing smoke. Wear self-
contained breathing apparatus and full protective gear.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Containers of product will burst from steam pressure under prolonged fire conditions.
6. ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Avoid breathing vapors. Absorb and sweep up spills immediately and transfer to suitable containers for possible land application according to label use
or for disposal. Check local, state and federal regulations for proper disposal.
CAUTION: Keep spills and cleaning runoff out of municipal sewers and open bodies of water.
7. HANDLING AND STORAGE
HANDLING: Wash hands after handling, and before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove clothing
immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. Remove PPE immediately after
handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into
clean clothing.
O O
STORAGE: Store above 28 F/-2.2 C or agitate before use. Do not contaminate water, food, or feed by storage or disposal.
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MATERIAL SAFETY DATA SHEET CHASER庐 2 AMINE
Personal Protective Equipment (PPE): Applicators and other handlers must wear: long sleeved shirt and long pants, waterproof gloves, shoes plus
socks, and protective eyewear. For containers over 1 gallon, but less than 5 gallons: Mixers and loaders who do not use a mechanical system (such
as probe and pump) to transfer contents of the container must wear coveralls or a chemical-resistant apron in addition to other required PPE. Discard
clothing and other absorbent materials that have been drenched or heavily contaminated with this product鈥檚 concentrate. Do not reuse them. Follow
manufacturer鈥檚 instructions for cleaning and maintaining PPE. If no instructions for washables, use detergent and hot water. Keep and wash PPE
separately from other laundry. After each day of use, clothing or PPE must no be reused until it has been cleaned.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: For containers of 5 gallons or more: A mechanical system (such as probe and pump) must be used for
transferring the contents of the container. If the contents of a non-refillable pesticide container are emptied, the probe
must be rinsed before removal. If the mechanical system is used in a manner that meets the requirements listed in
the Worker Protection Standard (WPS) for agricultural pesticides [40CFR 170.240 (d)(4)], the handler PPE
requirements may be reduced or modified as specified in the WPS.
When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets with requirements listed in the
Worker Protection Standard (WPS) for agricultural pesticides [40CFR 170.240 (d)(4-6)], the handler PPE
requirements may be reduced or modified as specified in the WPS.
RESPIRATORY PROTECTION: Not normally required, if vapors or dusts exceed acceptable levels, wear a MSHA/NIOSH approved pesticide respirator.
EYE PROTECTION: Chemical goggles or shielded safety glasses.
SKIN PROTECTION: Wear protective clothing: long-sleeved shirts and pants, shoes plus socks. Wear waterproof gloves.
OSHA PEL 8 hr TWA ACGIH TLV-TWA
3 3
2,4-D Acid 10 mg/m 10 mg/m
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE AND ODOR: Clear amber liquid with mild amine odor SOLUBILITY: Soluble
SPECIFIC GRAVITY (Water = 1): 1.173 g/ml BULK DENSITY: 9.79 lbs/gal pH: 7.5-8.5
O O
VAPOR PRESSURE: Not established BOILING POINT: 178 F/81.1 C
PERCENT VOLATILE (by volume): Not established EVAPORATION RATE: Not established
Note: These physical data are typical values based on material tested but may vary from sample to sample.
Typical values should not be construed as a guaranteed analysis of any specific lot or as specification items.
10. STABILITY AND REACTIVITY
STABILITY: Stable CONDITIONS TO AVOID: Avoid heat conditions.
INCOMPATIBILITY: Strong oxidizers or acids.
HAZARDOUS DECOMPOSITION PRODUCTS: Nitrogen oxide and hydrogen chloride may be formed under fire conditions.
HAZARDOUS POLYMERIZATION: Will not occur.
11. TOXICOLOGICAL INFORMATION
Acute Oral LD50 (male rat): 1576 mg/kg Acute Dermal LD50 (male rabbit): 1744 mg/kg
Eye Irritation (rabbit): Severe irritation with possible permanent corneal injury Skin Irritation (rabbit): Severe irritation with prolonged exposure
Acute Inhalation LC50 (rat): >2.0 mg/L. Skin Sensitization (guinea pig): Not established
Carcinogenic Potential: None listed in OSHA, NTP, IARC or ACGIH
12. ECOLOGICAL INFORMATION
This product is toxic to aquatic invertebrates. Drift or runoff may adversely affect aquatic invertebrates and non-target plants. Do not apply directly to
water, to areas where surface water is present, or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of
equipment wash waters.
13. DISPOSAL CONSIDERATIONS
Do not reuse containers. Plastic Containers: Triple rinse (or equivalent), then offer for recycling at an ACRC site or by reconditioning, or puncture and
dispose of in a sanitary landfill, or, if allowed by state and local authorities, by burning. If burned stay out of smoke. Metal Containers: Triple rinse (or
equivalent). Then offer for recycling, or puncture and dispose in a sanitary landfill. Consult federal, state, or local disposal authorities for approved
alternative procedures. Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal law and may
contaminate groundwater. Do not contaminate water, food, or feed by storage or disposal.
14. TRANSPORT INFORMATION
DOT Shipping Description: LESS THAN 36 GALLONS: NOT REGULATED BY USDOT FOR SDURFACE TRANSPORTATION.
36 GALLONS AND GREATER: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,4-D), 9, UN3082, III, MARINE POLLUTANT ERG
GUIDE 171
U.S. Surface Freight Classification: COMPOUND, TREE OR WEED KILLING, NOI (NMFC 50320, SUB 2:CLASS: 60)
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MATERIAL SAFETY DATA SHEET CHASER庐 2 AMINE
15. REGULATORY INFORMATION
NFPA & HMIS Hazard Ratings: NFPA HMIS
3 Health 0 Least 3 Health
1 Flammability 1 Slight 1 Flammability
1 Instability 2 Moderate 1 Reactivity
3 High J PPE
4 Severe
SARA Hazard Notification/Reporting
SARA Title III Hazard Category: Immediate __Y__ Fire __N__ Sudden Release of Pressure __N__
Delayed __Y__ Reactive __N__
Reportable Quantity (RQ) under U.S. CERCLA: 2,4-D Acid (CAS: 94-75-7) 100 lbs
SARA, Title III, Section 313: 2,4-D Acid (CAS: 94-74-7) 28.4%; Triethylamine salt of Triclopyr (CAS: 57213-69-1) 15.2%
RCRA Waste Code: Not listed
CA Proposition 65: Not listed
16. OTHER
MSDS STATUS: New
PREPARED BY: Registrations and Regulatory Affairs REVIEWED BY: Environmental/ Regulatory Services
庐Chaser is a registered trademark
*2,4-D Acid equivalent: 28.4%; 2.78 lb/gal.
**Triclopyr acid equivalent: 10.9%; 1.07 lb/gal.
Although the information and recommendations set forth herein (hereinafter 鈥淚nformation鈥?) are presented in good faith and believed to be correct,
VERDICON, the manufacturer or the seller makes no representations as to the completeness or accuracy thereof. Information is supplied upon the
condition that the persons receiving it will make their own determination as to its suitability for their purposes prior to use.
The product covered by this information sheet is furnished 鈥渁s is鈥? by VERDICON, the manufacturer or the seller, and is subject only to the warranties, if
any, that appear on the product鈥檚 label or are otherwise expressly provided herein.
Except as expressly provided on the product鈥檚 label or otherwise provided herein, no warranties, guarantees, or representations of any kind, either express
or implied, or by usage of trade, statutory or otherwise, are made by VERDICON, the manufacturer or the seller with regard to the product or use of the
product, including, but not limited to, merchantability, fitness for a particular purpose, use or eligibility of the product for any particular trade usage.
Except as expressly stated herein, VERDICON, the manufacturer or the seller makes no warranty of results to be obtained by use of the product covered
by this information. Buyer鈥檚 or user鈥檚 exclusive remedy, and the total liability of VERDICON, the manufacturer or the seller, shall be limited to damages not
exceeding the cost of the product. No agent or employee of VERDICON, the manufacturer or the seller is authorized to amend the terms of this warranty
disclaimer or the product鈥檚 label or to make a representation or recommendation different from or inconsistent with the label of this product.
IN NO EVENT SHALL VERDICON, THE MANUFACTURER OR THE SELLER BE LIABLE FOR CONSEQUENTIAL, SPECIAL OR INDIRECT
DAMAGES RESULTING FROM THE USE, HANDLING, APPLICATION, STORAGE OR DISPOSAL OF THIS PRODUCT OR FOR DAMAGES IN THE
NATURE OF PENALTIES AND THE BUYER AND USER WAIVE ANY RIGHT THEY MAY HAVE TO SUCH DAMAGES.
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